The Laboratory for Research on the Structure of Matter (LRSM)

1999 Publications

Primary Support, 1999

• Aranda-Espinoza, H., Chen, Y., Dan, N., Lubensky, T.C., Nelson, P., Ramos, L., and Weitz, D.A., "Self-Limiting, Two-Dimensional Colloidal Aggregates Formed on Bilayer Vesicles," Science 285, 394-397 (1999).
   
• Arkles, B., Berry, D. H., Composto, R. J., Figge, L. K., Gonzalez, G. B. and Wallace, W. E., "Characterization of New Spin-on-Glass Films Prepared by Thermal and UV
  Ozone Conversion Methods, Thin Solid Films 345, 244-254 (1999)*.
   
• Chen, I.-W., "Structural Origin of Relaxor Ferroelectrics-Revisited," J. Phys. Chem. Solids 61, 197-208 (1999).
   
• Chen, I.-W. and Wang, Y., "Activation Field in (Pb,La)(Zr,Ti)O3 Ferroelectric Thin Films," Appl. Phys. Lett., 75, 4186 (1999).
   
• Claye, A. and Fischer, J. E., "Short-Range Order in Disordered Carbons: Where Does the Li Go?" Electrochimica Acta. 45, 107-120 (1999).
   
• Composto, R. J., Berry, D. H., Arkles, B., Figge, L. K., Gonzalez, G. B., Pan, Q. and Wallace, W. E., "Spin-on-Glass Thin Films Prepared from a Novel Polysilsesquioxane by Thermal and Ultraviolet-Irradiation Methods," Thin Solid Films 345, 244-254 (1999).
   
• Davies, P. K. and Akbas, M. A., "Growth of the Chemically Ordered Domains in PMN-type Relaxor Ferroelectrics," Ferroelectrics 221, 27-36 (1999).
   
• Egami, T., "Microscopic Model of Relaxor Phenomena in Pb Containing Mixed Oxides," Ferroelectrics 222, 163 (1999).
   
• Egami, T., "Microscopic Model of Relaxor Phenomena in Pb Containing Mixed Oxides," Ferroelectrics 222, 421-428 (1999).
   
• Heiney, P. A., Stetzer, M. R., Mindyuk, O. Y., DiMasi, E., McGhie, A. R., Liu, H. and Smith, A. B. III, "Langmuir Films of Amphiphilic Crown Ethers," J. Phys. Chem. B 103, 6206-6214 (1999).
   
• Kalinin, S. V. and Bonnell, D. A., "Dynamic Behavior Of Domain-Related Topography and Surface Potential on the BaTiO3 (100) Surface By Variable Temperature Scanning Surface Potential Microscopy," Zeitschrift für Metallkund (Dec. 1999). *
   
• Lee, K. K., Vohs, J. M and DiNardo, N. J., "HREELS Studies of Vapor-Deposited Polyaniline on Ag(110)," Surface Science 420, 65-80 (1999).
   
• Lee, K. K., Vohs, J. M and DiNardo, N. J., "HREELS Studies of Vapor-Deposited Polyaniline on Ag(110)," Surface Science, 420, L115-L121 (1999).
   
• Lin, V. S.-Y., Iovine, P. M., DiMagno, S. G. and Therien, M. J., "Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays. Syntheses of Dipyrrylmethane and (5,15-Diphenylporphinato)zinc(II)," Inorg. Syntheses. Accepted for publication.
   
• Mindyuk, O. Y., Stetzer, M. R., Gidalevitz, D., Heiney, P. A., Nelson, J. C. and Moore, J. S., "Structure of a Phenylacetylene Macrocycle at the Air-Water Interface," Langmuir 15, 6897- 6900 (1999).
   
• Oslanec, R., Genzer, J., Faldi, A., Composto, R. J., and Garrett, P. D., "Surface Enrichment in a Miscible Random Copolymer Blend: Influence of Polydispersity and Architecture," Macromolecules 32, 4098 - 4105 (1999). *
   
• Pettey, D. and Lubensky, T. C., "Stability of Texture and Shape of Circular Domains of Langmuir Monolayers," Phys. Rev. E 59, 1834-1845 (1999).
   
• Reichl, J. A. and Berry, D. H., "Recent Progress in Transition Metal-Catalyzed Reactions of the Silicon, Germanium, and Tin," Adv. in Organomet. Chem. 43, 197-265 (1999).
   
• Sharma, J., Berry, D. H., Composto, R. J. and Dai, H.-L., "UV Laser Induced Formation of Thin Silicon Oxide Films from the Precursors: ß -Chloroethyl Silsesquioxane," J. Mat. Res. 14, 990-994 (1999). *
   
• Tanaka, I., Ohhara, T., Niimura, N., Ohashi, Y., Jiang, Q., Berry, D. H. and Bau, R., "The Classical Structure of TaCp2(H)(SiMe2H)2," J. Chem. Res. (S), 14-15 (1999).
   
• Zapotocky, M., Ramos, L., Poulin, P., Lubensky, T.C., and Weitz, D.A., "Particle-Stabilized Defect Gel in Cholesteric Liquid Crystals," Science 283, 209-212 (1999).
  

*acknowledges use of Shared Experimental Facilities

Partial Support, 1999

• Angerer, W. E., Yang, N., Yodh, A. G., Khan, M. A. and Sun, C. J., "Ultrafast Second-Harmonic Generation Spectroscopy of GaN Thin Films on Sapphire," Phys. Rev. B 59, 2932- 2946 (1999).
   
• Aranda-Espinoza, H., Chen, Y.,Dan, N., Lubensky, T. C., Nelson, P., Ramos, L. and Weitz, D. A., "Electrostatic Repulsion of Positively Charged Vesicles and Negatively Charged Objects," Science 285, 394-397 (1999).
   
• Balasubramanian, S., Mundy, C. J. and Klein, M. L., Trimethylaluminum: A Computer Study of the Condensed Phases and the Gas Dimer," J. Phys. Chem. B. 102, 10136-10141 (1999).
   
• Blasie, J. K. and Timmins, P., "Neutron Scattering in Structural Biology and BiomolecularMaterials," MRS Bulletin 24, 40-47 (1999). *
   
• Burteaux, B., Claye, A., Smith, B. W., Monthioux, M., Luzzi, D. E. and Fischer, J. E., "Abundance of Encapsulated C60 in Single-Wall Carbon Nanotubes," Chem. Phys. Lett. 310, 21 (1999).
   
• Chen, I.-W., and Engineer, M., "A Model for Fatigue Crack Growth in Grain Bridging Ceramics," J. Amer. Ceram. Soc. 82, 3549-60 (1999).
   
• Chen, X., Moser, C. C., Pilloud, D. L., Gibney, B. R. and Dutton, P. L., "Engineering Oriented Heme Protein Maquette Monolayers through Surface Residue Charge Distribution Patterns," J. Phys. Chem B 103, 9029-9037 (1999).
   
• Clauss, W., Zhang, J., Bergeron, D. J. and Johnson, A. T., "Application and Calibraton of a Quartz Needle Sensor for High Resolution Scanning Force Mircoscopy," J. Vac. Sci. and Tech. 17, 1309-13112 (1999).
   
• Clauss, W., Bergeron, D. J., Freitag, M., Kane, C. L., Mele, E. J. and Johnson, A. T., "Electron Backscattering on Single-Wall Carbon Nanotubes Observed by Scanning Tunneling Microscopy," Europhysics Lett. 47, 601-607 (1999).
   
• Crocker, J., C., Matteo, J. A., Dinsmore, A. D. and Yodh, A. G., "Entropic Atraction and Repulsion in Binary Colloids Probed with a Line Optical Tweezer," Phys. Rev. Lett. 82, 4352-4355 (1999). *
   
• Diekmann, G. R., Lear, J. D., Zhong, Q., Klein, M. L., DeGrado, W. F. and Sharp, K. A., "Exploration of the Structural Features Defining the Conduction Properties of a Synthetic Ion Channel," Biophys. J. 76, 618-630 (1999).
   
• Dinsmore, A. D. and Yodh, A. G., "Entropic Confinement of Colloidal Spheres to Corners on Silicon Substrates," Langmuir 15, 314-316 (1999).
   
• Dioumaev, V. K., Plössl, K., and Berry, D. H. "Formation and Interconversion of Ruthenium-Silene and 16-Electron Ruthenium Silyl Complexes," J. Am. Chem. Soc., 121, 8391-8392 (1999).
   
• Discher, B. M., Won, Y. Y., Ege, D. S., Lee, J. C-M., Bates, F. S., Discher, D. E. and Hammer, D. A., "Polymersomes: tough Vesicles made From Diblock Copolymers," Science 284, 143- 146 (1999).
   
• Dvorak, J. and Dai, H.-L., "Optical Reflectivity Changes Induced by Adsorption on Metal Surfaces: The Origin and Applications to Monitoring Adsorption Kinetics," J. Chem. Phys., in press (2000).
   
• Edwards, A. M., Zhang, K., Nordgren, C. E. and Blasie, J. K., "Polarized XAS on Vectorially-Oriented Single Monolayers of Cytochrome c," J. Synchrotron Rad. 6, 411-413 (1999); Biophys J. 76, A18 (1999).
   
• Fischer, J. E. and Johnson, A.T., "Electronic Properties of Carbon Nanotubes," Current Opinion in Solid State and Materials Science 4, 28-33 (1999).
   
• Fischer, J. E., Claye, A. and Lee, R. S., "Crystallography of Intercalated Nanotube Lattices," Liq. Cryst., accepted for publication (1999).
   
• Fischer, J. E. and Johnson, A.T., "Electronic Properties of Carbon Nanotubes," Current Opinion in Solid State and Materials Science 4, 28-33 (1999).
   
• Genzer, J. and Composto, R. J., "The Interface Between Immiscible Polymers Studied by Low Energy Forward Recoil Spectrometry and Neutron Reflectivity," Polymer 40, 4223-4228 (1999)*.
   
• Genzer, J. and Composto, R. J., "The Interface Between Immiscible Polymers Studied by Low Energy Forward Recoil Spectrometry and Neutron Reflectivity," Polymer 40, 4223-4228 (1999)*.
   
• Gibney, B. R., Rabanal, F., Skalicky, J. J., Wand, A. J. and Dutton, P. L., "Iterative Protein Redesign," J. American Chemical Society 121, 4952-4960 (1999).
   
• Gibney, B. R. and Dutton, P. L., "Histidine Placement in De Novo-Designed Heme Proteins," Protein Science 8, 1888-1898 (1999).
   
• Huey, B., Lisjak, D., Bonnell, D. A., "Nanoscale Variations in Potential at Ceramics Surfaces and Interfaces," J. Amer. Ceram. Society 82, 1941-44 (1999). *
   
• Huff, B. J., Krich, J. J., and Collings, P. J., "Helix Inversion in the Chiral Nematic and Isotropic Phases of a Liquid Crystal," Phys. Rev. E, submitted (1999).
   
• Hyslop, A. G., Kellett, M. A., Iovine, P. M. and Therien, M. J., "Suzuki Porphyrins: New Synthons for the Fabrication of Porphyrin-Containing Supramolecular Assemblies, J. Am.Chem. Soc. 217, U1119, Part 1 (1999).
   
• Kneller, L. R., Edwards, A. M., Majkrzak, C. F., Berk, N. F., Krueger, S. and Blasie, J. K., "Hydration State of a Single Cytochrome c Monolayer Vectorially-Oriented at a Soft Interface Investigated via Neutron Interferometry," Biophys J. 76, A219 (1999). *
   
• Kuhlmann-Wilsdorf, D. and Winey, K. I., "Does Plastic Deformation Proceed Near Thermodynamic Equilibrium? The Case of Shear Induced Kink Bands in Lamellar Diblock Copolymers," J. Applied Physics 85, 6392-6399 (1999).
   
• Lam, H.-T. and Vohs, J. M., "Surface Reactions of Trimethylgallium on MOVPE-Grown GaN(0001)," Surface Science 426 (1999).
   
• Laurer, J. H., Pinheiro, B. S., Polis, D. L. and Winey, K. I., "Persistence of Surface-Induced Alignment in Block Copolymers Upon Large Amplitude Oscillatory Shear Processing," Macromolecules 32, 4999-5003 (1999). *
   
• Lefebvre, J., Lynch, J. F., Llaguno, M., Radosavljevic, M. and Johnson, A. T., "Single Wall Carbon Nanotube Circuits Assembled with an Atomic Force Microscope," Applied Physics Letters 75, 3014-3016 (1999).
   
• Lewis, S. P. and Rappe, A. M., "Structural and Vibrational Properties of Carbon Monoxide Adlayers on the Copper (001) Surface," J. Chem. Phys. 110, 4619-4633 (1999).
   
• Menon, M. and Chen, I.-W., "Bimaterial Composties via Colloidal Rolling Techniques, I. Microstructure Evolution during Rolling," J. Amer. Ceram. Soc. 82 [12] 3413-21 (1999).
   
• Menon, M. and Chen, I.-W., "Bimaterial Composties via Colloidal Rolling Techniques, II. Sintering Behavior and Thermal Stresses," J. Amer. Ceram. Soc. 82 [12] 3422-29 (1999).
   
• Menon and Chen, I.-W., "Bimaterial Composties via Colloidal Rolling Techniques, III. Mechanical Properties," J. Amer. Ceram. Soc. 82[12] 3430-40 (1999).
   
• Mindyuk, O. Y., Heiney, P. A., Josefowicz, J. Y., Schuhmacher, P., and Ringsdorf, H., "Structural Phase Transition in Ultrathin Films of Disk-Shaped Molecules," Liq. Cryst. 29, 31-36 (1999).
   
• Montgomery, J. K. Akbas, M. A. and Davies, P. K., "1:1 Ordered Domain Growth in La-Doped PMN-Type Relaxors," J. Amer. Ceram. Soc. 82, 3481-3484 (1999).
   
• Nelson, P., "Transport of Torsional Stress in DNA," Proc. National Acad. Science 96, 14342-14347 (1999).
   
• Polis, D. L., Smith, S. D., Terrill, N. J., Ryan, A. J., Morse, D. C. and Winey, K. I., "Shear-Induced Lamellar Rotation Observed in a Diblock Copolymer by In Situ Small Angle X-Ray Scattering," Macromolecules 32, 4668-4676 (1999).
   
• Polis, D. L., Ryan, A. J., Smith, S. D. and Winey, K. I., "Nature of Viscoelasticity in Lamellar Diblock Coppolymers: Contraction Correlated to Strain Localization," Phys. Rev. Lett. 83, 2861-2864 (1999).
   
• Ramer, N. J. and Rappe, A. M., "Designed Nonlocal Pseudopotentials for Enhanced Transferability," Phys. Rev. B 59, 12471 (1999).
   
• Ramer, N. J. and Rappe, A. M., "Application of a New Virtual Crystal Approach for the Study of Disordered Perovskites," J. Phys. Chem. Solids 61, 315-320 (2000).
   
• Ramos, L., Lubensky, T. C., Dan, N., Nelson, P., and Weitz, D. A., "Surfactant-Mediated Two-Dimensional Crystallization of Colloidal Crystals," Science 286, 2325-2328 (1999).
   
• Rosenflanz, A. and Chen, I.-W., "Kinetics of Phase Transformations in SiAlON Ceramics I. Effects of Cation Size, Composition and Temperature," J. Europ. Ceram. Soc. 19, 2325-35 (1999).
   
• Rosenflanz, A. and Chen, I.-W., "Kinetics of Phase Transformations in SiAlON Ceramics II. Reaction Paths," J. Europ. Ceram. Soc. 19, 2337-48 (1999).
   
• Rosenflanz, A. and Chen, I.-W., "Phase Relationships and Stability of a '-SiAlON," J. Amer. Ceram. Soc. 82 [4] 1025-36 (1999).
   
• Saitta, A. M., Soper, P. D., Wasserman, E. and Klein, M. L., "Influence of a Know on the Strength of a Polymer Strand," Nature 399 46-48 (1999).
   
• Tarek, M., Tu, K., Klein, M. L. and Tobias, D. J., "Molecular Dynamics Simulations of Supported Phospholipid/Alkanethiol Bilayers on a Gold (111) Surface," Biophys. J. 77, 964- 972 (1999).
   
• Triantafillou, M. and Kamien, R. D., "Polymer Shape Anisotropy and the Depletion Interaction," Phys. Rev. E 59, 5621 (1999).
   
• Walsh, S. T. R., Cheng, H., Bryson, J. W., Roder, H. and DeGrado, W. F., "Solution Structure and Dynamics of a De Novo Designed Three-Helix Bundle Protein," PNAS 96 (1999).
   
• Walter, E. J. and Rappe, A. M., "Accurate and Efficient Determination of Chemisorption Energies Using Pseudopotentials," Surf. Sci. 427, 11 (1999).
   
• Wang, H., Troxler, T., Yeh, A-G. and Dai, H.-L., "In-Situ, Nonlinear Optical Probe of Surfactant Adsorption on the Surface of Micro-Particles in Colloids," Langmuir, in press (1999).
   
• Wideman, T., Remsen, E. E., Zank, G. A. and Sneddon, L. G., "Polymeric Precursors for BN and SiNCB Ceramic Fibers," in Precursor Derived Ceramics, ed. J. Bill, F. Wakai and F. Aldinger, Wiley-VCR, 103-112 (1999).
   
• Winey, K. I., Laurer, J. H. and Kirkmeyer, B., "Ionic Aggregates in Partically Zn-Neutralized Poly(ethylene-co-methacrylic acid) Ionomers: Shape, Size and Size Dispersity," Macromolecules, accepted (1999). *

*acknowledges use of Shared Experimental Facilities

Shared Experimental Facilities, 1999

• Brown, K. and Bonnell, D. A., "Segregation in YAG I: Experimental Study of Single Crystal Surfaces," J. Am. Ceramic Society 82, 2423-2430 (1999).
   
• Brown, K. and Bonnell, D. A., "Segregation in YAG II: Theoretical Predictions Based on Ionic Space Charge Models," J. Am. Ceramic Society 82, 2431-2441 (1999).
   
• Chesnokov, S. A., Nalimova, V. A., Thess, A., Rinzler, A. G., Smalley, R. E. and Fischer, J. E., "Mechanical Energy Storage in Carbon Nanotube Springs," Phys. Rev. Lett. 82, 343 (1999).
   
• Effah-Kaufmann, E., Ducheyne, P., Radin, S., Bonnell, D. A., Composto, R., "Serum Proteins Affect the Surface Reactions Layer on Bioactive Glass," Bioceramics 12 ed, H. Ohgushi, G. Hastings, T. Yoshikawa World Publishing Co Pte. Ltd. (1999) 379-382
   
• Ferrizz, R. M., Egami, T. and Vohs, J. M., "The Reaction of Ethylene on a Model Automotive Emissions Control Catalyst," Catal. Lett. 61, 33 (1999).
   
• Fischer, J. E. and Johnson, A. T., "Electronic Properties of Carbon Nanotubes," Current Opinion in Solid State and Materials Science 4, 23 (1999).
   
• Kaufmann, E. A., B. E., Ducheyne, P., Radin, S., Bonnell, D. A. and Composto, R. J., "Serum Proteins Affect the Surface Reaction Layer of Bioactive Glass," Prof. 12 th Int'l Symposium on Ceramics in Medicine, Bioceramics 12, 379-82 (1999).
   
• Maliszewskyj, N. C., Mindyuk, O. Y., Heiney, P. A., Josefowicz, J. Y., Schumacher, P. and Ringsdorf, H., "Structural Phase Transition in Ultrathin Films of Disk-Shaped Molecules," Liquid Crystals 26, 31-36 (1999).
   
• Mukundan, R., Davies, P. K., and Worrell, W. L., "Preparation and Characterization of Compounds in the BaBiO3 Ba(Ce1-xGdx)O3-x/2 System," J. Materials Research 14, 124-131 (1999).
   
• Nemes, N. M., Fischer, J. E., Baumgartner, G., Forro, L. and Anossy, A. J., "Conduction Electron Spin Resonance in the Superconducting State of K3C60," AIP Conf. Prof. in press (1999).
   
• Their, K.-F., Goze, C., Mehring, M., Rachdi, F., Yildirim, T. and Fischer, J. E., "Metallic Properties of the Ternary Fullerides ABa2C60 (A=K, Rb, Cs)," Phys. Rev. B. 59, 10536 (1999).
   
• Valant, M and Davies, P. K., "Synthesis and Dielectric Properties of Pyrochlore Solid Solutions in the Bi2O3-ZnO-Nb2O5-TiO2 System," J. Materials Science 34, 5437-5442 (1999).