The Laboratory for Research on the Structure of Matter (LRSM)

2002 Publications

Primary Support, 2002

• Barsotti, R., Fischer, J. E., Lee, C. H., Mahmood, J., Adu, C. K. W. and Eklund, P. C., "Imaging, structural and chemical analysis of silicon nanowires," Applied Phys. Lett. 81, 2866 (2002).
   
• Biercuk, M., Llaguno, M. C., Radosavljevic, M., Hyun, J. K., Fischer, J. E. and Johnson, A. T., "Carbon nanotube composites for thermal management," Applied Physics Lett. 80, 2767- 2769 (2002).
   
• Cebers, A., and Janmey, P., "Shape instabilities in charged lipid domains," J. Phys. Chem. B 106, 12351-12353 (2002).
   
• Composto, R. J., Walters, R. and Genzer, J., "Ion beam techniques and their application in polymer science" Materials Science and Engineering Reports: A Review Journal. Elsevier Science, Switzerland.  (38/3-4 pp. 107-180) 1 July 2002.
   
• Discher, B. M., H. Bermudez, Y.-Y. Won, D. A. Hammer, F. S. Bates, and Discher, D. E., "Crosslinked copolymer vesicles with broadly tunable stability," J. Physical Chemistry B 106(11); 2848-2854 (2002).
   
• Eklund, P. C., Prahdan, B. K., Kim, U. J., Fischer, J. E., Friedman, A. D., Holloway, B. C., Jordan, K. and Smith, M. W., "Large scale production of single walled carbon nanotubes using ultrafast pulses from a free electron laser," Nanoletters 2, 561 (2002).
   
• Fletcher, J. T. and Therien, M. J., "Strongly coupled porphyrin arrays featuring both p-cofacial and linear-p-conjugative interactions," Inorg. Chem. 41, 331-341 (2002).
   
• Fletcher, J. T. and Therien, M. J., "Extreme electronic modulation of the cofacial porphyrin structural motif," J. Am. Chem. Soc. 124, 4298-4311 (2002).
   
• Freitag, M. and Johnson, A. T., "Nanoscale characterization of carbon nanotube field-effect transistors," page 513 - 516, Proceedings of the XVI International Winterschool, Kirchberg, Tyrol, 2002, AIP Conference Proceedings 633 (Melville, New York, 2002).
   
• Hone, J., Llaguno, M. C., Biercuk, M. J., Johnson, A. T., Batlogg, B., Benes, Z. and Fischer, J. E., "Thermal properties of carbon nanotubes and nanotube-based materials," Applied Physics A 74, 339-343 (2002).
   
• Johnson, A. T., "Memory effect and role of defects in carbon nanotube field effect transistors," page 526 -530, Proceedings of the XVI International Winterschool, Kirchberg, Tyrol, 2002, AIP Conference Proceedings 633 (Melville, New York, 2002).
   
• Johnson, A. T., Freitag, M., Radosavljevic, M., Kalinin, S. V. and Bonnell, D. A., "Role of defects in carbon nanotube circuits," Int'l Journal of Nanoscience 1, 247-254 (2002).
   
• Kalinin, S. V., Freitag, M., Johnson, A. T. and Bonnell, D. A., "Carbon nanotubes as a tip calibration standard for electrostatic scanning probe microscopies," Applied Physics Lett. 81, 754 -756 (2002).
   
• Kalinin, S. V., Suchomel, M. R., Davies, P. K., Bonnell, D. A., "Potential and impedance imaging of polycrystalline BiFeO3 ceramics," J. of the American Ceramic Society 85(12), 3011-3017 (2002).
   
• Kalinin, S., Bonnell, D., Freitag, M. and Johnson, A. T., "Tip-gating effect in scanning impedance imaging of nanoelectronic devices," Appl. Phys. Lett. 81, 5219-5221 (2002).
   
• Kalinin, S. and Bonnell, D., "Contrast mechanism maps for piezoresponse force microscopy," J. Mat. Res. 17, 936-939 (2002).
   
• Kalinin, S. and Bonnell, D., "Imaging mechanism of piezoresponse force microscopy of ferroelectric Phys. Rev. B 64, 125408 (2002).
   
• Lacoste, D., Collings, P. J., and Lubensky, T. C., "Effective index of refraction, optical rotation, and circular dichroism in the cholesteric blue phase III," Phys. Rev. E 65, 031717/1-11 (2002).
   
• Lacoste, D., Lau, A. W. C., and Lubensky, T. C., "Phase transitions in lyotropic nematic gels," Euro. Phys. J. E 8, 403-411 (2002) [cond-mat/0202262].
   
• Lee, J. C-M., Santore, M., Bates, F. S. and Discher, D. E., "From Membranes to Melts, Rouse to Reptation: Diffusion in Polymersome Versus Lipid Bilayers," in Communications to the Editor Macromolecules 35, 323-326 (2002).
   
• Mach, P., Wilzius, P., Megens, M., Weitz, D. A., Lin, K.-H., Lubensky, T. C., and Yodh, A. G., "Switchable bragg diffraction from liquid crystal in colloid-templated structures," Europhys. Lett. 58, 679-85 (2002). *
   
• Nordgren, E., Tobias, D. J., Klein, M. L. and Blasie, J. K., "Molecular dynamics simulations of a hydrated protein vectorially-oriented at hydrophobic vs. hydrophilic soft surfaces," Biophys. J. 83, 2906-2917 (2002).
   
• Popov, G., Kalinin, S. V., Alvarez, T. Emge, T., Greenblatt, M. and Bonnell, D., "Micromagnetic and magnetoresistance studies of ferromagnetic La0.83Sr0.13MnO2.98 crystals," Phys. Rev. B 64 064426 (2002).
   
• Radosavljevic, M. Freitag, M., Thadani, K. V. and Johnson, A. T., "Nonvolatile molecular memory elements based on ambipolar nanotube field effect transistors," NanoLetters 2, 761 - 764 (2002).
   
• Susumu, K. S. and Therien, M. J., "Decoupling optical and potentiometric band gaps in p-conjugated materials" J. Am. Chem. Soc, 124, 8550-8552 (2002).
   
• Uyeda, H. T., Zhang, Y., Wostyn, K., Asselberghs, I., Clays, K., Persoons, A. and Therien, M. J., "Unusual frequency dispersion effects of the nonlinear optical response in highly conjugated (Polypyridyl)metal-(Porphinato)zinc(II) Chromophores," J. Am. Chem. Soc. 124, 13806-13813 (2002).
   
• Walters, R. M., Sohn, K. E., Winey, K. I., and Composto, R. J., "Investigation into local acid environment in poly(ethylene-ran-methacrylic acid) ionomers," J. Poly. Sci. Physics, 41, 2833-2841 (2002).
  

*acknowledges use of Shared Experimental Facilities

Partial Support, 2002

• Aranda-Espinoza, H., Carl, P., Leterrier, J. F., Janmey, P. and Discher, D. E., "Domain unfolding in neurofilament sidearms: effects of phosphorylation and ATP," FEBS Lett 531, 397-401 (2002).
   
• Bermudez, H., Brannon, A. K., Hammer, D. A., Bates, F. S. and Discher, D. E., "Molecular weight dependence of polymersome membrane elasticity and stability," Macromolecules 35:8203-8208 (2002).
   
• Blasie, J. K., Strzalka, J. and Zheng, S., "Solution to the phase problem for specular X-ray or neutron reflectivity," Phys. Rev. Lett., submitted.
   
• Bocquet, L., Losert, W., Schalk, D., Lubensky, T. C., and Gollub, J. P., "Granular Shear Flow Dynamics and Forces, Experiment and Continuum Theory," Phys. Rev. E 65, 011307, Part 1 (2002).
   
• Bonnell, D. and Kalinin, S., "Scanning Impedance Microscopy of an Active Schottky Barrier Diode," J. Applied Physics 91, 832-39 (2002).
   
• Bonnell, D. and Kalinin, S., "Scanning impedance microscopy: from impedance spectra to impedance images," Microscopy Today 2, 22 (2002).
   
• Borisevich, A. Y., Davies, P. K., "Crystalline structure and dielectric properties of Li1+x-yNb1-x-3yTix+4yO3 M-phase solid solutions," J. of the American Ceramic Society 85(3), 573-578 (2002).
   
• Borisevich, A. and Davies, P. K "La(Li1/3Ti2/3)O3: a new 1:2 ordered perovskite" J. of Solid State Chemistry 17, 2130-2140 (2002).
   
• Borisevich, A. Y., Davies, P. K., "Synthesis and dielectric properties of Li1-x+yTa1-x-3yTix+4yO3 M-phase solid solutions," J. of the American Ceramic Society 85(10), 2487-2491(2002).
   
• Calvalcanti-Adam, E. A., Shapiro, I. M., Macarak, E. J., Composto, R. J., El Ghannam, A., Adams, C. S., "RGD peptides immobilized on a mechanically deformable surface promote osteoblast differentiation," J. Bone Min. Res., in press.
   
• Chen, X., Discher, B., Pilloud, D. L., Gibney, B. R., Moser, C. C., and Dutton, P. L. "De novo design of a cytochrome b maquette for electron transfer and coupled reactions on electrodes," J. Phys. Chem. B 106: 617-624, (2002).
   
• Cheng, R. P. and DeGrado, W. F., "Long-range interactions stabilize the fold of a non-natural oligomer," J. Am. Chem. Soc. 124, 11564-11565 (2002).
   
• Cooper, V. R., Grinberg, I., Martin, N. R. and Rappe, A. M., "Local Structure of PZT," AIP Conf. Proc. 626, 26-35 (2002).
   
• Dai, Q.-H., Tommos, C., Fuentes, E. J., Bloomberg, M. R. A., Dutton, P. L. and Wand, A. J., "Structure of a de novo designed protein model of radical enzymes," J. Am. Chem. Soc. 124, 10952-10953 (2002).
   
• DiCostanzo, L., Wade, H., Geremia, S., Randaccio, L., Pavone, V., DeGrado, W. F., Lombardi, A., "Toward the de novo design of a catalytically active helix bundle: a substrate-accessible carboxylate-bridged dinuclear metal center," J. Am. Chem. Soc. 123, 12749-12757 (2001).
   
• Discher, D. E. and Eisenberg, A., "Polymer vesicles," Science 297, 967-973 (2002).
   
• Farber, L., Valant, M., Akbas, M. A., Davies, P. K., "Cation ordering in Pb(Mg1/3Nb2/3)O3-Pb(Sc1/2Nb1/2)O3 (PMN-PSN) solid solutions," J. of the American Ceramic Society 85(9), 2319-2324 (2002).
   
• Farber, L., Levin, I., Borisevich, A., Grey, I. E., Roth, R. S., Davies, P. K., "Structural study of Li1+x-yNb1-x-3yTix+4yO3 solid solutions," J. of Solid State Chemistry 166(1), 81-90 (2002).
   
• Feng, T. and Vohs, J. M., "TPD-TGA and Calorimetric Study of the Partial Oxidation of Methanol on TiO2-Supported Vanadium Oxide," J. Catal., 208 (2002) 301.
   
• Fischer, J. E., "Chemical doping of single-wall carbon nanotubes," Accounts of Chem. Research 30, 21 (2002).
   
• Forsthoefel,K. M., Pender, M. J. and Sneddon, L. G., "Chemical precursor routes to nanostructured non-oxide ceramics" MRS Symposium Proceedings 53, 60-64 (2002).
   
• Getahun, Z., Huang, C-Y., Wang, T., León, B. D., DeGrado, W. F. and Gai, F., "Using nitrile-derivatized amino acids as infrared probes of local environment," J. Am. Chem. Soc.125, 405-411 (2003).
   
• Ghirlanda, G., Lear, J. D., Ogihara, N. L., Eisenberg, D. and DeGrado, W. F., "A hierarchic approach to the design of hexameric helical barrels," J. Mol. Biol. 319, 243-253 (2002).
   
• Gibney, B.R., Skalicky, J.J. Wand, A. J. and Dutton, P. L., "Determining the global topology of a dimeric protein maquette via redesign," Submitted to: Protein Science 2003.
   
• Gratkowski, H., Dai, Q.-H., Wand, A. J., DeGrado, W. F. and Lear, J. D., "Cooperativity and specificity of association of a designed transmembrane peptide," Biophys. J. 83, 1613-1619 (2002).
   
• Grinberg, I., Cooper, V. R. and Rappe, A. M., "Relationship between local structure and phase transitions of a disordered solid solution," Nature 419, 909-911 (2002).
   
• Grinberg, I., Yourdshahyan, Y. and Rappe, A. M., "CO on Pt (111) puzzle: A possible solution", J. Chem. Phys. 117, 2264-2270 (2002).
   
• Hornbaker, D. J., Kahng, S.-J., Misra, S., Smith, B. W., Johnson, A. T., Mele, E. J., Luzzi, D. E. and Yazdani, A., "Mapping the one dimensional electronic states of nanotube peapod structures" Science 295, 828 (2002) (cover story).
   
• Huang, C. Y., Getahun, Z., Zhu, Y. J., Klemke, J. W., DeGrado, W. F. and Gai, F., "Helix formation via conformation diffusion search," Proc. Natl. Acad. Sci. USA 99, 2788-2793 (2002).
   
• Huang, C. Y., He, S., DeGrado, W. F., McCafferty, D. G. and Gai, F., "Light-induced helix formation," J. Am. Chem. Soc. 124, 12674-12675 (2002).
   
• Juhas, P., Davies, P. K., Akbas, M. A., "Chemical order and dielectric properties of lead scandium tungstate relaxors," AIP Conference Proceedings 626(Fundamental Physics of Ferroelectrics 2002), 108-116.
   
• Kalinin, S., Johnson, A. T., Bonnell, D. A., "Domain Polarity and Temperature Induced Potential Inversion
  on the BaTiO3 (100) Surface," Applied Physics Letters 91 (2002) 3816.
   
• Kane, C. L., Mele, E. J., Johnson, A. T., Luzzi, D. E., Smith, B. W., Hornbaker, D. J. and Yazdani, A., "Theory of scanning tunneling spectroscopy of fullerene peapods" Phys. Rev. B 66, 235423 (2002).
   
• Lau, A.W.C., Lin, K-H., and Yodh, A. G., "Entropic interactions in suspensions of semi-flexible rods: short-range effects of flexibility," Phys. Rev. E 66, 020401-1-020401-4 (2002). *
   
• Lee, J. C-M., Santore, M., Bates, F. S. and Discher, D. E., "From membranes to melts, Rouse to reptation: diffusion in polymersome versus lipid bilayers," Communications to the Editor Macromolecules 35: 323-326 (2002).
   
• Mach, P., Wiltzius, P., Megens, M., Weitz, D.A., Lin, K.-H., Lubensky, T.C., Yodh, A.G., "Electro-optic Response and Switchable Bragg Diffraction for Liquid Crystal in Colloid-templated Materials," Phys. Rev. E 65, 031720, Part 1(2002). *
   
• Marsh, E. N. G., DeGrado, W. F., "Noncovalent self-assembly of a heterotetrameric diron protein," Proc. Natl. Acad. Sci. 99, 5150-5154 (2002).
   
• Mele, E. J. and Kral, P., "Electric Polarization of Heteropolar Nanotubes as a Geometric Phase," Phys. Rev. Lett. 88, 056803 (2002).
   
• Mele, E. J. and Yazdani, A., "Probing the Electronic States of Nanotube Peapods with the Scanning Tunneling Microscope" Applied Physics A 76, 1-6 (2002).
   
• Pender, M. J., Forsthoefel, K. and Sneddon, L. G., "The Design, Syntheses and Applications of Group 13 Molecular and Polymeric Precursors to Advanced Ceramics" in Group 13 Chemistry: Fundamental Research, Materials Science and Catalysis Shapiro, P. and Atwood, D. eds., American Chemical Society Symposium Series, ACS: Washington, D. C., 2002, 168-180.
   
• Percec, V., Popov, A. V., Ramirez-Castillo, E., Monteiro, M., Barboiu, B., Weichold, O., Asandei, A. D. and Mitchell, C. M., "Aqueous room temperatuve metal-catalyzed living radical polymerisation of vinyl chloride," J. Am. Chem. Soc. 124, 4940-4941 (2002).
   
• Raugei, S. and Klein, M. L., "An ab initio study of water molelcules in the bromide ion salvation shell," J. Chem. Phys. 116, 196-202 (2002).
   
• Redmore, N. P., Rubtsov, I. V. and Therien, M. J., "Synthesis, excited-state dynamics, and reactivity of a directly-linked pyromellitimide-(Porphinato)zinc(II) Complex," Inorg. Chem. 41, 566-570 (2002).
   
• Rogers, C. L. and Rappe, A. M., "Geometric formulation of quantum stress fields," Phys. Rev. B 65, 224117 (1-8) (2002). Saitta, A. M. and Klein, M. L., "Influence of a knot on the stretching-induced crystallization of a polymer," J. Chem. Phys. 116, 5333-5336 (2002).*
   
• Santore, M. M., Discher, D. E., Won, Y.-Y., Bates, F. S. and Hammer, D. A., "Effect of surfactant on unilamellar polymeric vesicles: altered membrane properties and stability in the limit of weak solvent partitioning," Langmuir 18:7299-7308 (2002).
   
• Smith, B. W., Russo, R. M., Chikkannanavar, S. B. and Luzzi, D. E., "High-yield Synthesis and One-Dimensional Structure of C60 Encapsulated in Single Wall Carbon Nanotubes, " J. Appl. Phys. 91, 9333-9340 (2002).
   
• Summa, C. M., Rosenblatt, M. M., Hong, J. K., Lear, J. D. and DeGrado, W. F., "Computational de novo design and characterization of an A(2)B(2) diiron protein," J. Mol. Biol. 321, 923-938 (2002).
   
• Tang, J. X., Janmey, P. A., Lyubartsev, A., and Nordenskiold, L. "Metal ion-induced lateral aggregation of filamentous viruses fd and M13," Biophys J 83, 566-81 (2002).
   
• Tew, G. N., Liu D. H., Chen, B., Doerksen, R. J., Kaplan, J., Carroll, P.J., Klein, M.L., DeGrado, W. F., "Supramolecular chemistry and self-assembly special feature: de novo design of biomimetic antimicrobial polymers," Proc. Natl. Acad. Sci. 99, 5110-5114 (2002).
   
• Tronin, A., Edwards, A. M., Wright, W.W., Vanderkooi, J.M. and Blasie, J.K., "Orientational distributions for cytochrome c on polar & nonpolar soft surfaces by polarized total internal reflection fluorescence," Biophys. J. 82: 996-1003 (2002).
   
• Wang, H. and Composto, R. J., "Wetting and Phase Separation in Polymer Blend Films: Identification of Four Thickness Regimes with Distinct Morphological Pathways. Interface Science, Special Issue: Polymers at Interfaces. (in press)
   
• Wang, H. and Composto, R. J., "Kinetics of surface and interfacial fluctuations in phase separating Polymer blend film," Macromolecules 35, 2799-2809 (2002).
   
• Wong, G. S., Concepcion, M. R. and Vohs, J. M., "Oxidation of Methanol to Formaldehdye on Vanadia Films Supported on CeO2(111)," J. Phys. Chem. B, 106 (2002) 6451.
   
• Yourdshahyan, Y. and Rappe, A. M., "Structure and energetics of alkanethiol adsorption on the Au (111) surface," J. Chem. Phys. 117, 825-33 (2002).
   
• Zhang, Y., Omolola Eniola, A., Graves, D. J. and Hammer, D. A., "Specific Adhesion of Micron-Sized Colloids to Surfaces Mediated by Hybridizing DNA Chains," submitted, Langmuir (2002).
   
• Zhang J., Alsayed A., Lin K.-H., Sanyal S., Zhang F., Pao, W.J., Balagurusamy, V.S.K., Heiney, P.A., Yodh A.G., "Template-directed convective assembly of three-dimensional face-centered-cubic colloidal crystals" Appl. Phy.s Lett. 81 (17): 3176-3178, (2002). *.
  

*acknowledges use of Shared Experimental Facilities

Shared Experimental Facilities, 2002

• Dakskobler, A., T. Kosmac, T. and Chen, I.-W., "Paraffin-based process for processing layered composites with cellular microstructures," J. Am. Ceram. Soc., 85 [4], 1013-15 (2002).
   
• Freitag, M., Kalinin, S. V., Dawn A. Bonnell, D. A., and Johnson, A. T., "Role of single defects in electronic transport through carbon nanotube field effect transistors," Phys. Rev. Lett. 89, 216801 (2002).
   
• Haggenmueller, R., Zhou, W., Fischer, J. E. and Winey, K. I., "Mechanical and structural investigation of highly aligned single-walled carbon nanotube polymer composites," J. Nanoscience and Nanotechnology , in press.
   
• Kang, Y. K., Rubtsov, I. V., Iovine, P. M., Chen, J. and Therien, M. J., "Distance dependence of electron transfer in rigid, cofacially compressed, p-stacked porphyrin-bridge-quinone systems," J. Am. Chem. Soc. 124, 8275-8279 (2002).
   
• Kirkmeyer, B. P., Taubert, A., Kim, J.-S. and Winey, K. I. "Vesicular ionic aggregates in poly(styrene-co-methacrylic acid) ionomers neutralized with Cs," Macromolecules 35, 2648-2653 (2002).
   
• Kirkmeyer, B. P., Puetter, P. R., Yahil, A. and Winey, K. I., "Ionomer morphologies: Deconvolution of STEM images," J. Polym. Sci.: Polym. Phys., 40, 2833-2841 (2002).
   
• Lin, V. S.-Y., Iovine, P. M., DiMagno, S. G. and Therien, M. J., "Dipyrryl and porphyrinic precursors to supramolecular conjugated (Porphinato)metal Arrays. Syntheses of dipyrrylmethane and (5,15-Diphenylporphinato)zinc(II)," Inorg. Syntheses 33, 55-61 (2002).
   
• Qiao, L., Ryan, A. J. and K. I. Winey, "A correlation between lamellar contraction and applied shear stress in diblock copolymer," Macromolecules 35, 3596-3600 (2002).
   
• Schwarz, M., Zerr, A., Kroke, E., Miehe,G., Chen, I.-W., Heck, M., Thybusch, B., Toe, B., and Riedel, R., "Spinel sialons," Angew. Chem. Int. Ed. 41 [5]. 789-93 (2002).
   
• Taubert, A. and Winey, K. I., "Imaging and x-ray microanalysis of poly(ethylene-ran-methacrylic acid) ionomer melt neutralized with Sodium," Macromolecules 35, 7419-7426 (2002).
   
• Vavro, J., Llaguno, M. C., Satishkumar, B. C., Luzzi, D. E. and Fischer, J. E., "Electrical and Thermal Properties of C60-filled Single-Wall Carbon Nanotubes", Appl. Phys. Letters 80, 1450-1452 (2002).
   
• Walters, R. W., Sohn, K. E., Winey, K. I. and Composto, R. J., "Local acid environments in poly(ethylene-ran-methacrylic acid) ionomers," Journal of Polymer Science: Part B: Polymer Physics Edition 41, 2833-2841, 2002.
   
• Zenotchkine, M., Shuba, R., Kim, J.-S. and Chen, I. W., "Effect of seeding on the microstructure and mechanical properties of a-SiAlON: I. Y-SiAlON," J. Am. Ceram. Soc., 85 [5] 1254-59 (2002).
   
• Zenotchkine, M., Shuba, R., Kim, J.-S. and Chen, I. W., "Effect of seeding on the microstructure and mechanical properties of a-SiAlON: II. Ca-SiAlON," J. Am. Ceram. Soc., 85 [5] 1260-67 (2002).
   
• Zenotchkine, M., Shuba, R., Kim, J.-S. and Chen, I. W., "Effect of heating schedule on the microstructure and fracture toughness of a-SiAlON: cause and solution," J. Am. Ceram. Soc., 85 [7] 1882-84 (2002).